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2 edition of Reactions of indene derivatives. found in the catalog.

Reactions of indene derivatives.

Priit Einbaum

Reactions of indene derivatives.

by Priit Einbaum

  • 166 Want to read
  • 15 Currently reading

Published by University of Salford in Salford .
Written in English


Edition Notes

PhD thesis, Chemistry.

SeriesD35051/81
ID Numbers
Open LibraryOL21685146M

ChemInform Abstract: Synthesis of Highly Substituted Indene Derivatives by Broensted Acid Catalyzed Friedel-Crafts Reaction of Homoallylic Alcohols. Article in Tetrahedron Letters 55(29) Reaction of Singlet Oxygen with transPropenylanisole. Formation of [2 + 2] Products with Added Acid. The Journal of Organic Chemistry , 65 (21), Cited by:

Hydrosilylation of indene with various hydrosilanes in the presence of Speier's catalyst leads in high yields to 1‐indanyl‐substituted silanes. In contrast to these results, the hydroboration of indene with HBC1 2 SMe 2 results in the 2‐indanyl‐substituted product. Further reactions of these derivatives . Synthetic reactions of dimethylformamide. XXII. Formation and preparation of formyl derivatives of indene , Vol. 30, Issue 8, pp. – A. Holý and Z. Arnold Synthetic reactions of dimethylformamide. XXI. The formation of aromatic compounds during the formylation reactions , Vol. 30, Issue 1, pp. 53–

James H. Lewis, Jonathan G. Stine, in Drug-Induced Liver Disease (Third Edition), Sulindac (Clinoril) This indene derivative, which bears a structural similarity to indomethacin, was approved for use in the United States in after several years of study in Europe. The overall incidence of adverse side effects has been 25% and toxicity requiring withdrawal of the drug is seen in 5–7. Abstract. Fluorohalocarbene, generated from CHCl 2 F using phase transfer catalysis, reacts with indene, cyclopentadiene, and their alkyl derivatives to form 2-fluoronaphthalenes or fluorobenzenes in 9–60% yield. Reactions proceed through formation of unstable fluorochlorocyclopropanes, which rearrange selectively independently of their stereochemical configuration into the corresponding Cited by: 5.


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Reactions of indene derivatives by Priit Einbaum Download PDF EPUB FB2

The reaction of 2-(chloromethyl)phenylboronic acid with alkynes in the presence of a Rh(I) catalyst gave indene derivatives in high yields. The regioselectivity depends on the steric nature of the substituent on the alkynes. Studies on indene derivatives.

Part VII. New reactions of triketoindane and experiments with hydrindantin and related compounds. A series of novel indene-derived retinoic acid receptor α (RARα) agonists have been designed Reactions of indene derivatives.

book synthesized. The use of receptor binding, cell proliferation and cell differentiation assays demonstrated that most of these compounds exhibited moderate RARα Cited by: 4. Indene or naphthalene derivatives are readily prepared in moderate to excellent yields with high regio- and stereoselectivity under very mild reaction conditions by the reaction of acetylenic malonates and ketones with I 2, ICl, or NIS.

The resulting iodides can be further elaborated using palladium-catalyzed coupling by: Studies on indene derivatives. Part III. The constitution and some reactions of bishydroxyindone. The photochemical reduction of triketohydrindeneCited by: 4.

3-Iodo-1H-indene derivatives are synthesized by iodonium-promoted 5-endo-dig carbocyclization of 2-substituted ethynylmalonates. Various 2-substituted ethynylmalonates bearing aryl- alkyl- and ether-protected propargyl alcohols were successfully converted to cyclized by: Synthesis of 1-alkylated indenecarboxylates by reaction between 1-acetoxy-1H-indenecarboxylate and Grignard reagents in the presence of catalytic amounts of LiCuBr 2.

A series of novel indene-derived retinoic acid receptor α (RARα) agonists have been designed and synthesized. The use of receptor binding, cell proliferation and cell differentiation assays demonstrated that most of these compounds exhibited moderate RARα binding activity and potent antiproliferative activity.

In particular, 4-((3-isopropoxy-2,3-dihydro-1H-indenyl)-carbamoyl)benzoic acid Cited by: 4. Books shelved as derivatives: Options, Futures and Other Derivatives by John C. Hull, The Big Short: Inside the Doomsday Machine by Michael Lewis, Trader. The iodocyclization reactions of diethyl 2-(2-(1-alkynyl)phenyl)malonates and diethyl 2-(2-(3-hydroxypropynyl)benzyl)malonates to give iodinated indene derivatives and   Hydrosilylation of indene with various hydrosilanes in the presence of Speier's catalyst leads in high yields to 1‐indanyl‐substituted silanes.

In contrast to these results, the hydroboration of indene with HBC1 2 SMe 2 results in the 2‐indanyl‐substituted product.

Further reactions of these derivatives are : J. Dautel, S. Abele. The reaction of α,β-unsaturated aldehyde 11 with BBr 3 gave the indene derivative To the best of our knowledge, synthesis of an indene derivative from the reaction of α,β-unsaturated aldehyde such as 11 with BBr 3 has not be reported previously.

The formation of an indene-derivative in the presence of BBr 3 is a new : Cetin Bayrak, Cetin Bayrak, Abdullah Menzek. Reactions. Indane can also be converted in a catalytic reactor to other aromatics such as xylene. Indane is used in the synthesis of sulofenur. Derivatives.

Derivatives include compounds such as 1-methyl-indane and 2-methyl-indane (where one methyl group is attached to the five carbon ring), 4-methyl-indane and 5-methyl-indane (where one methyl group is attached to the benzene ring), various Boiling point: °C ( °F; K). The reaction of n BuNa with indene in the presence of a tridentate N-donor ligand, PMDETA, gave the monomeric product, [{Na + (PMDETA)}Ind] (35), demonstrating the η 5-binding between the metal ion and the Cp-ring in the solid state.

89 In contrast, its lithium analogue 33 exhibits η 2-binding. 83 In the presence of TMEDA, indenyl anions aggregate with sodium cations to form a polymeric product, [{Na. Synthesis of highly substituted indene derivatives by Bronsted acid catalyzed Friedel-Crafts reaction of homoallylic alcohols.

Xiaoxiang Zhang, Wan Teng Teo, Weidong Rao, Dik-Lung Edmond Ma, Chung-Hang Duncan Leung, Philip Wai Hong by: The rate constant for the vapor phase reaction of indene with photochemically produced hydroxyl radicals can be estimated to be X cu cm/molecule-sec at 25 °C which corresponds to an atmospheric half-life of about hours at an atmospheric concn of.

Lewis acid-catalyzed formation of indene derivatives via tandem reactions of arylacetylenes with the cations generated from 2-silylmethyl cyclopropyl carbinols V. Yadav, N.

Kumar and M. Parvez, Chem. Commun.,  The first synthesis of phenylpropanoid derivative bromophenols including natural products: Formation of an indene derivative compound Cetin Bayrak, Abdullah Menzek Article Lewis Acid Mediated Reactions of Zirconacyclopentadienes with Aldehydes: One‐Pot Synthetic Route to Indene and Cyclopentadiene Derivatives from Aldehydes and Benzyne or Alkynes Changjia Zhao Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education College of Chemistry and Molecular Engineering Peking.

This indene derivative, which bears a structural similarity to indomethacin, was approved for use in the United States in after several years of study in Europe. The overall incidence of adverse side effects has been 25% and toxicity requiring withdrawal of the drug is seen in 5–7% of patients [–].

The palladium-catalyzed carboannulation and arylation reaction of propargylic carbonates with in situ generated organozinc compounds produced an important new class of indene derivatives.

The reaction proceeded under mild conditions, and indene products were isolated in good to excellent yields.Regiodivergent Synthesis of Functionalized Indene Derivatives via Pt-Catalyzed Rautenstrauch Reaction of Propargyl Carbonates Jinbo Zhao and Daniel A.

Clark* * Center for Science and Technology, Department of Chemistry, Syracuse University, Syracuse, New YorkUnited States, Email: daclar01   One-step synthesis of benzene derivatives, β-substituted naphthalenes and acenes by the cycloaromatization of enediynes and enyne-allenes by Bergman, Myers-Saito and Shmittel.

Mechanisms of cycloaromatization resulting in the formation of fulvene and indene systems. Heterocyclization involving enyne-carbodiimides.